I did create the directory before trying to mount.
mount gives the following,
osmc@osmc:~$ mount
/dev/mmcblk0p2 on / type ext4 (rw,noatime,stripe=1024,data=ordered)
devtmpfs on /dev type devtmpfs (rw,relatime,size=371420k,nr_inodes=92855,mode=755)
proc on /proc type proc (rw,relatime)
sysfs on /sys type sysfs (rw,nosuid,nodev,noexec,relatime)
tmpfs on /dev/shm type tmpfs (rw,nosuid,nodev)
devpts on /dev/pts type devpts (rw,nosuid,noexec,relatime,gid=5,mode=620,ptmxmode=000)
tmpfs on /run type tmpfs (rw,nosuid,nodev,mode=755)
tmpfs on /run/lock type tmpfs (rw,nosuid,nodev,noexec,relatime,size=5120k)
tmpfs on /sys/fs/cgroup type tmpfs (ro,nosuid,nodev,noexec,mode=755)
cgroup on /sys/fs/cgroup/systemd type cgroup (rw,nosuid,nodev,noexec,relatime,xattr,release_agent=/lib/systemd/systemd-cgroups-agent,name=systemd)
cgroup on /sys/fs/cgroup/cpu,cpuacct type cgroup (rw,nosuid,nodev,noexec,relatime,cpu,cpuacct)
cgroup on /sys/fs/cgroup/blkio type cgroup (rw,nosuid,nodev,noexec,relatime,blkio)
cgroup on /sys/fs/cgroup/devices type cgroup (rw,nosuid,nodev,noexec,relatime,devices)
cgroup on /sys/fs/cgroup/freezer type cgroup (rw,nosuid,nodev,noexec,relatime,freezer)
cgroup on /sys/fs/cgroup/net_cls type cgroup (rw,nosuid,nodev,noexec,relatime,net_cls)
systemd-1 on /home/osmc/mnt/diskstation/video type autofs (rw,relatime,fd=22,pgrp=1,timeout=300,minproto=5,maxproto=5,direct)
systemd-1 on /proc/sys/fs/binfmt_misc type autofs (rw,relatime,fd=23,pgrp=1,timeout=300,minproto=5,maxproto=5,direct)
debugfs on /sys/kernel/debug type debugfs (rw,relatime)
mqueue on /dev/mqueue type mqueue (rw,relatime)
fusectl on /sys/fs/fuse/connections type fusectl (rw,relatime)
configfs on /sys/kernel/config type configfs (rw,relatime)
/dev/mmcblk0p1 on /boot type vfat (rw,noatime,fmask=0022,dmask=0022,codepage=437,iocharset=ascii,shortname=mixed,errors=remount-ro)
sysfs on /sys/devices/system/cpu/cpu0/cpufreq/scaling_cur_freq type sysfs (rw,nosuid,nodev,noexec,relatime)
tmpfs on /run/user/1000 type tmpfs (rw,nosuid,nodev,relatime,size=75148k,mode=700,uid=1000,gid=1000)
And (sudo) mount -a gives absolutely no feedback at all.